Nothing wrong with that IMO. Just be aware Harvester brings and is tested with Longhorn, and i am not aware any method of disabling Longhorn in Harvester (but probably its not impossible).
Ceph and Longhorn is developed for different use cases and at the end of the day both can be used for permanent storage, but totally different architecture and therefore different approaches. Once a Suse engineer told in a storage workshop, that you probably do not need Ceph, but if your use case fits Ceph's design goals then nothing else will do :)
Putting Ceph storage on Longhorn provided volumes, that is a double headache and fraction of the performance (they both need physical disks)